Bromidotricarbon­yl[4-iodo-N-(pyridin-2-yl­methyl­idene)aniline-κ2 N,N′]rhenium(I)

نویسندگان

  • Saeed Dehghanpour
  • Ali Mahmoudi
چکیده

In the title compound, [ReBr(C(12)H(9)IN(2))(CO)(3)], the coordination geometry of the Re(I) ion is a distorted fac-ReC(3)BrN(2) octa-hedron, arising from the N,N'-bidentate ligand, a bromide ion and a facial arrangement of three carbonyl ligands. The dihedral angle between the aromatic rings in the 4-iodo-N-(pyridin-2-yl-methyl-idene)aniline ligand is 46.2 (3)°. The bromide ion and its corresponding trans CO mol-ecule are disordered over two sets of sites in a 0.966 (3):0.034 (3) ratio.

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Bromidotricarbon­yl[4-chloro-N-(2-pyridyl­methyl­idene)aniline-κ2 N,N′]rhenium(I)

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010